The complete dissolution of a spherical thin shell covering the inner free-surface of a matrix of infinite extension containing a spherical pore has been theoretically investigated in the framework of the diffusion-controlled evolution formalism of a strained substitutional binary alloy at constant temperature, assuming the outer flux of the diffusing species in the matrix is constant at an infinite-distance from the shell. When the diffusion is assumed to only occur in the matrix phase and strain is present, the dissolution-time of the shell has been analytically determined and the effects of the misfit strain, elastic coefficient heterogeneities and initial outer radius of the shell on the dissolution-time have been discussed. The case where the central region is filled by the matrix phase has been also addressed.

Colin, J., Bergamaschini, R. (2026). Dissolution of a strained spherical shell embedded in a matrix. JOURNAL OF CRYSTAL GROWTH, 682(1 May 2026) [10.1016/j.jcrysgro.2026.128548].

Dissolution of a strained spherical shell embedded in a matrix

Bergamaschini R.
2026

Abstract

The complete dissolution of a spherical thin shell covering the inner free-surface of a matrix of infinite extension containing a spherical pore has been theoretically investigated in the framework of the diffusion-controlled evolution formalism of a strained substitutional binary alloy at constant temperature, assuming the outer flux of the diffusing species in the matrix is constant at an infinite-distance from the shell. When the diffusion is assumed to only occur in the matrix phase and strain is present, the dissolution-time of the shell has been analytically determined and the effects of the misfit strain, elastic coefficient heterogeneities and initial outer radius of the shell on the dissolution-time have been discussed. The case where the central region is filled by the matrix phase has been also addressed.
Articolo in rivista - Articolo scientifico
Crystal morphology; Diffusion; Dissolution model; Misfit strain;
English
20-feb-2026
2026
682
1 May 2026
128548
embargoed_20280220
Colin, J., Bergamaschini, R. (2026). Dissolution of a strained spherical shell embedded in a matrix. JOURNAL OF CRYSTAL GROWTH, 682(1 May 2026) [10.1016/j.jcrysgro.2026.128548].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/611281
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