The complete dissolution of a spherical thin shell covering the inner free-surface of a matrix of infinite extension containing a spherical pore has been theoretically investigated in the framework of the diffusion-controlled evolution formalism of a strained substitutional binary alloy at constant temperature, assuming the outer flux of the diffusing species in the matrix is constant at an infinite-distance from the shell. When the diffusion is assumed to only occur in the matrix phase and strain is present, the dissolution-time of the shell has been analytically determined and the effects of the misfit strain, elastic coefficient heterogeneities and initial outer radius of the shell on the dissolution-time have been discussed. The case where the central region is filled by the matrix phase has been also addressed.
Colin, J., Bergamaschini, R. (2026). Dissolution of a strained spherical shell embedded in a matrix. JOURNAL OF CRYSTAL GROWTH, 682(1 May 2026) [10.1016/j.jcrysgro.2026.128548].
Dissolution of a strained spherical shell embedded in a matrix
Bergamaschini R.
2026
Abstract
The complete dissolution of a spherical thin shell covering the inner free-surface of a matrix of infinite extension containing a spherical pore has been theoretically investigated in the framework of the diffusion-controlled evolution formalism of a strained substitutional binary alloy at constant temperature, assuming the outer flux of the diffusing species in the matrix is constant at an infinite-distance from the shell. When the diffusion is assumed to only occur in the matrix phase and strain is present, the dissolution-time of the shell has been analytically determined and the effects of the misfit strain, elastic coefficient heterogeneities and initial outer radius of the shell on the dissolution-time have been discussed. The case where the central region is filled by the matrix phase has been also addressed.| File | Dimensione | Formato | |
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Colin-Bergamaschini-2026-Journal of Crystal Growth-AAM.pdf
embargo fino al 20/02/2028
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