For the first time, the tetrafluorobenzyl unit has been considered as a C-H⋯anion binding motif. In synergy with imidazolium groups within a bowl-shaped receptor, it has allowed for the effective binding of chloride in solution. Remarkable affinity was observed in organic-water mixtures.
Amendola, V., Bergamaschi, G., Boiocchi, M., Legnani, L., Presti, E., Miljkovic, A., et al. (2016). Chloride-binding in organic-water mixtures: The powerful synergy of C-H donor groups within a bowl-shaped cavity. CHEMICAL COMMUNICATIONS, 52(72), 10910-10913 [10.1039/c6cc04978h].
Chloride-binding in organic-water mixtures: The powerful synergy of C-H donor groups within a bowl-shaped cavity
Legnani L.;
2016
Abstract
For the first time, the tetrafluorobenzyl unit has been considered as a C-H⋯anion binding motif. In synergy with imidazolium groups within a bowl-shaped receptor, it has allowed for the effective binding of chloride in solution. Remarkable affinity was observed in organic-water mixtures.
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