Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocy-cle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations.
Pappalardo, A., Ballistreri, F., Toscano, R., Chiacchio, M., Legnani, L., Grazioso, G., et al. (2021). Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts. CATALYSTS, 11(4) [10.3390/catal11040465].
Alkene Epoxidations Mediated by Mn-Salen Macrocyclic Catalysts
Legnani, Laura;
2021
Abstract
Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocy-cle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations.
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