The synthesis and the structure of the novel trianion [fe3Rh3(CO)17]3- is reported; the metal framework of this 88 valence electron bimetallic cluster is unusual, and consists of an Fe2Rh3 trigonal bipyramid with iron and rhodium atoms in apical sites and a dangling Fe atom attached to the apical Rh.
Ceriotti, A., DELLA PERGOLA, R., Longoni, G., Heaton, B., Demartin, F., Manassero, M. (1986). BIMETALLIC IRON-RHODIUM CARBONYL CLUSTERS - SYNTHESIS AND X-RAY STRUCTURE OF THE NOVEL [FE3RH3(CO)17] (3-) TRI-ANION. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 311(1-2), C31-C33 [10.1016/0022-328X(86)80245-5].
BIMETALLIC IRON-RHODIUM CARBONYL CLUSTERS - SYNTHESIS AND X-RAY STRUCTURE OF THE NOVEL [FE3RH3(CO)17] (3-) TRI-ANION
DELLA PERGOLA, ROBERTO;
1986
Abstract
The synthesis and the structure of the novel trianion [fe3Rh3(CO)17]3- is reported; the metal framework of this 88 valence electron bimetallic cluster is unusual, and consists of an Fe2Rh3 trigonal bipyramid with iron and rhodium atoms in apical sites and a dangling Fe atom attached to the apical Rh.
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