Nature's recipe: A theoretical study analyzes how the environment of the [FeFe] hydrogenase's catalytic cofactor affects its chemical properties, particularly the relative stability of complexes with bridging and terminal hydride ligands (see picture; Fe teal, S yellow, C green, N blue, O red, H gray). The results help to elucidate key rules for the design of bioinspired synthetic catalysts for H2 production. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
Bruschi, M., Greco, C., Kaukonen, M., Fantucci, P., Ryde, U., & De Gioia, L. (2009). Influence of the [2Fe]H Subcluster Environment on the Properties of Key Intermediates in the Catalytic Cycle of [FeFe] Hydrogenases: Hints for the Rational Design of Synthetic Catalysts. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 48(19), 3503-3506 [10.1002/anie.200900494].
Citazione: | Bruschi, M., Greco, C., Kaukonen, M., Fantucci, P., Ryde, U., & De Gioia, L. (2009). Influence of the [2Fe]H Subcluster Environment on the Properties of Key Intermediates in the Catalytic Cycle of [FeFe] Hydrogenases: Hints for the Rational Design of Synthetic Catalysts. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 48(19), 3503-3506 [10.1002/anie.200900494]. | |
Tipo: | Articolo in rivista - Articolo scientifico | |
Carattere della pubblicazione: | Scientifica | |
Titolo: | Influence of the [2Fe]H Subcluster Environment on the Properties of Key Intermediates in the Catalytic Cycle of [FeFe] Hydrogenases: Hints for the Rational Design of Synthetic Catalysts | |
Autori: | Bruschi, M; Greco, C; Kaukonen, M; Fantucci, P; Ryde, U; De Gioia, L | |
Autori: | ||
Data di pubblicazione: | 6-apr-2009 | |
Lingua: | English | |
Rivista: | ANGEWANDTE CHEMIE. INTERNATIONAL EDITION | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.200900494 | |
Appare nelle tipologie: | 01 - Articolo su rivista |