Unprecedented bismuth complexes, based on the rarely used ditopic ligand N-oxide-2,2′-bipyridine (bp2mo), crystallizing as three polymorphs, α- (1), β- (2) and γ-[BiBr<inf>3</inf>(bp2mo)<inf>2</inf>] (3), exhibit phosphorescence with a quantum yield up to 17% for the crystal phase (1), while the complex displays a weak fluorescence in solution. A study of the luminescence properties combined with DFT/TDDFT calculations reveals that the lighting phenomenon originated by aggregation induced phosphorescence correlated with the weak intermolecular interactions present in the different crystal phases.

Toma, O., Mercier, N., Allain, M., Forni, A., Meinardi, F., Botta, C. (2015). Aggregation induced phosphorescent N-oxyde-2,2′-bipyridine bismuth complexes and polymorphism-dependent emission. DALTON TRANSACTIONS, 44(33), 14589-14593 [10.1039/c5dt01801c].

Aggregation induced phosphorescent N-oxyde-2,2′-bipyridine bismuth complexes and polymorphism-dependent emission

MEINARDI, FRANCESCO
Penultimo
;
2015

Abstract

Unprecedented bismuth complexes, based on the rarely used ditopic ligand N-oxide-2,2′-bipyridine (bp2mo), crystallizing as three polymorphs, α- (1), β- (2) and γ-[BiBr3(bp2mo)2] (3), exhibit phosphorescence with a quantum yield up to 17% for the crystal phase (1), while the complex displays a weak fluorescence in solution. A study of the luminescence properties combined with DFT/TDDFT calculations reveals that the lighting phenomenon originated by aggregation induced phosphorescence correlated with the weak intermolecular interactions present in the different crystal phases.
Articolo in rivista - Articolo scientifico
Aggregation induced phosphorescence, bismuth complexes
English
2015
44
33
14589
14593
none
Toma, O., Mercier, N., Allain, M., Forni, A., Meinardi, F., Botta, C. (2015). Aggregation induced phosphorescent N-oxyde-2,2′-bipyridine bismuth complexes and polymorphism-dependent emission. DALTON TRANSACTIONS, 44(33), 14589-14593 [10.1039/c5dt01801c].
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/88322
Citazioni
  • Scopus 34
  • ???jsp.display-item.citation.isi??? 33
Social impact