Fe-Cu octahedral carbide clusters, and the replacement of their labile halide ligands: synthesis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2-, [Fe4C(CO)12(CuCl)2]2-, [{Fe4Cu2C(CO)12(m-Cl)}2]2-, [Fe5C(CO)14(CuOC4H8)]- and [Fe4C(CO)12(CuNCMe)2]