The reactions between [Fe6C(CO)16]2- and CuCl yield selectively [Fe5C(CO)14(CuCl)]2-, [Fe4C(CO)12(CuCl)2]2-, or [{Fe4Cu2C(CO)12(m-Cl)}2]2-, depending on the Fe6/CuCl ratio. In these clusters, the halides can be substituted by solvent molecules. Their redox activity was studied by electrochemical methods. In the bridged dimer, the two cluster units resulted electronically not communicating
Della Pergola, R., Sironi, A., Garlaschelli, L., Strumolo, D., Manassero, C., Manassero, M., et al. (2010). Fe-Cu octahedral carbide clusters, and the replacement of their labile halide ligands: synthesis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2-, [Fe4C(CO)12(CuCl)2]2-, [{Fe4Cu2C(CO)12(m-Cl)}2]2-, [Fe5C(CO)14(CuOC4H8)]- and [Fe4C(CO)12(CuNCMe)2]. INORGANICA CHIMICA ACTA, 363, 586-594.
Citazione: | Della Pergola, R., Sironi, A., Garlaschelli, L., Strumolo, D., Manassero, C., Manassero, M., et al. (2010). Fe-Cu octahedral carbide clusters, and the replacement of their labile halide ligands: synthesis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2-, [Fe4C(CO)12(CuCl)2]2-, [{Fe4Cu2C(CO)12(m-Cl)}2]2-, [Fe5C(CO)14(CuOC4H8)]- and [Fe4C(CO)12(CuNCMe)2]. INORGANICA CHIMICA ACTA, 363, 586-594. |
Tipo: | Articolo in rivista - Articolo scientifico |
Carattere della pubblicazione: | Scientifica |
Titolo: | Fe-Cu octahedral carbide clusters, and the replacement of their labile halide ligands: synthesis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2-, [Fe4C(CO)12(CuCl)2]2-, [{Fe4Cu2C(CO)12(m-Cl)}2]2-, [Fe5C(CO)14(CuOC4H8)]- and [Fe4C(CO)12(CuNCMe)2] |
Autori: | Della Pergola, R; Sironi, A; Garlaschelli, L; Strumolo, D; Manassero, C; Manassero, M; Fedi, S; Zanello, P; Kaswalder, F; Zacchini, S |
Autori: | |
Data di pubblicazione: | 2010 |
Lingua: | English |
Rivista: | INORGANICA CHIMICA ACTA |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.ica.2009.01.025 |
Appare nelle tipologie: | 01 - Articolo su rivista |