Up to three PtPPh3 fragments, originating from [Pt(PPh3)2(C2H4)], can be added to [Re2(CO)10] affording [Re2Ptn(mu-C0)2n(CO)10-2n(PPh3)n] (n = 1,2,3) mixed metal clusters, with structures based on electron short (46 valence electrons) Re2Pt triangles condensed on the Re-Re hinge.

Ciani, G., Moret, M., Sironi, A., Beringhelli, T., D'Alfonso, G., DELLA PERGOLA, R. (1990). Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Pt n (µ-CO)2n (CO)10 - 2n (PPh3) n ](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium-platinum mixed-metal clusters. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1990(23), 1668-1670 [10.1039/C39900001668].

Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Pt n (µ-CO)2n (CO)10 - 2n (PPh3) n ](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium-platinum mixed-metal clusters

MORET, MASSIMO;DELLA PERGOLA, ROBERTO
1990

Abstract

Up to three PtPPh3 fragments, originating from [Pt(PPh3)2(C2H4)], can be added to [Re2(CO)10] affording [Re2Ptn(mu-C0)2n(CO)10-2n(PPh3)n] (n = 1,2,3) mixed metal clusters, with structures based on electron short (46 valence electrons) Re2Pt triangles condensed on the Re-Re hinge.
Articolo in rivista - Articolo scientifico
platinum, rhenium, metal cluster, heterometallic clusters
English
1990
1990
23
1668
1670
open
Ciani, G., Moret, M., Sironi, A., Beringhelli, T., D'Alfonso, G., DELLA PERGOLA, R. (1990). Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Pt n (µ-CO)2n (CO)10 - 2n (PPh3) n ](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium-platinum mixed-metal clusters. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1990(23), 1668-1670 [10.1039/C39900001668].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/8485
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