Novel surface-active monomers were synthesized by successive treatment of tert-butylperoxy-6-hydroxyhexanoate with maleic anhydride, 1,3-propane sultone and triethylamine or with maleic anhydride and poly(ethylene glycol) methyl ether. The surface-active properties of monomers were studied. The critical micelle concentrations (cmc) as well as the surface tension at the cmc were determined for obtained monomers. The synthesized compounds were shown to be suitable reactive surfactants for obtaining styrene latexes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Borzenkov, M., Hevus, O. (2012). Novel peroxide containing maleate surface active monomers for obtaining reactive polymers. MACROMOLECULAR SYMPOSIA, 315(1), 60-65 [10.1002/masy.201250508].
Novel peroxide containing maleate surface active monomers for obtaining reactive polymers
BORZENKOV, MYKOLAPrimo
;
2012
Abstract
Novel surface-active monomers were synthesized by successive treatment of tert-butylperoxy-6-hydroxyhexanoate with maleic anhydride, 1,3-propane sultone and triethylamine or with maleic anhydride and poly(ethylene glycol) methyl ether. The surface-active properties of monomers were studied. The critical micelle concentrations (cmc) as well as the surface tension at the cmc were determined for obtained monomers. The synthesized compounds were shown to be suitable reactive surfactants for obtaining styrene latexes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.