In this paper we report a variable temperature EPR investigation on auto-assembling inclusion compounds of tris(o-phenylenedioxy)cyclotriphosphazene (TPP), the nitroxide radical methyl ester of the 16-doxyl-stearic acid (16-dox), and diamagnetic co-guests of various polarities. By playing with the nature of the co-guest and the concentration of the radical we obtained radicals isolated, or in 1D clusters. Local order, dynamics and orientation of the guests have been obtained by simulations of the spectra of spin-carrying guests envisaged as probes. For the simulations, intra-channel and inter-channel radical pairs and trimers magnetic interactions have been modellized. The interest of similar compounds for 1D magnetic materials is discussed.

Barbon, A., Zoleo, A., Brustolon, M., Comotti, A., & Sozzani, P. (2008). One-dimensional clusters of 16-doxyl-stearate radicals in organic nanochannels as studied by electron paramagnetic resonance (EPR). INORGANICA CHIMICA ACTA, 361(14-15), 4122-4128 [10.1016/j.ica.2008.03.088].

One-dimensional clusters of 16-doxyl-stearate radicals in organic nanochannels as studied by electron paramagnetic resonance (EPR)

COMOTTI, ANGIOLINA;SOZZANI, PIERO ERNESTO
2008-03-23

Abstract

In this paper we report a variable temperature EPR investigation on auto-assembling inclusion compounds of tris(o-phenylenedioxy)cyclotriphosphazene (TPP), the nitroxide radical methyl ester of the 16-doxyl-stearic acid (16-dox), and diamagnetic co-guests of various polarities. By playing with the nature of the co-guest and the concentration of the radical we obtained radicals isolated, or in 1D clusters. Local order, dynamics and orientation of the guests have been obtained by simulations of the spectra of spin-carrying guests envisaged as probes. For the simulations, intra-channel and inter-channel radical pairs and trimers magnetic interactions have been modellized. The interest of similar compounds for 1D magnetic materials is discussed.
Articolo in rivista - Articolo scientifico
Scientifica
inclusion compounds,tris(o-phenylenedioxy)cyclotriphosphazene, TPP, EPR spectroscopy, radicals, guest dynamic
English
4122
4128
Barbon, A., Zoleo, A., Brustolon, M., Comotti, A., & Sozzani, P. (2008). One-dimensional clusters of 16-doxyl-stearate radicals in organic nanochannels as studied by electron paramagnetic resonance (EPR). INORGANICA CHIMICA ACTA, 361(14-15), 4122-4128 [10.1016/j.ica.2008.03.088].
Barbon, A; Zoleo, A; Brustolon, M; Comotti, A; Sozzani, P
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/6412
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