• Aiuto
  • Sfoglia

    • In this paper we report a variable temperature EPR investigation on auto-assembling inclusion compounds of tris(o-phenylenedioxy)cyclotriphosphazene (TPP), the nitroxide radical methyl ester of the 16-doxyl-stearic acid (16-dox), and diamagnetic co-guests of various polarities. By playing with the nature of the co-guest and the concentration of the radical we obtained radicals isolated, or in 1D clusters. Local order, dynamics and orientation of the guests have been obtained by simulations of the spectra of spin-carrying guests envisaged as probes. For the simulations, intra-channel and inter-channel radical pairs and trimers magnetic interactions have been modellized. The interest of similar compounds for 1D magnetic materials is discussed.

    SFX

    Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/6412

    Citazione: Barbon, A., Zoleo, A., Brustolon, M., Comotti, A., & Sozzani, P.E. (2008). One-dimensional clusters of 16-doxyl-stearate radicals in organic nanochannels as studied by electron paramagnetic resonance (EPR). INORGANICA CHIMICA ACTA, 361(14-15), 4122-4128.
    Tipo: Articolo in rivista - Articolo scientifico
    Carattere della pubblicazione: Scientifica
    Titolo: One-dimensional clusters of 16-doxyl-stearate radicals in organic nanochannels as studied by electron paramagnetic resonance (EPR)
    Autori: Barbon, A; Zoleo, A; Brustolon, M; Comotti, A; Sozzani, PE
    Autori interni: SOZZANI, PIERO ERNESTO
    COMOTTI, ANGIOLINA
    Data di pubblicazione: 23-mar-2008
    Lingua: English
    Rivista: INORGANICA CHIMICA ACTA
    Appare nelle tipologie:01 - Articolo su rivista

    File in questo prodotto:
    Non ci sono file associati a questo prodotto.
    • Citazioni

    I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
     
     
     
    Powered by IRIS-about IRIS-Privacy ed uso cookie
    Logo CINECA  Copyright © 2017