Super model: Diiron dithiolates exist in nature in [FeFe]-hydrogenase, for the purpose of making or oxidizing molecular hydrogen. Evidence for how H2 interacts with diiron complexes has been realized using model diiron dithiolato carbonyl complexes. The pathway for this interaction has been elucidated computationally as well as synthetically, by using silanes in place of H2.

Heiden, Z., Zampella, G., DE GIOIA, L., & Rauchfuss, T. (2008). [FeFe]-Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 47(50), 9756-9759 [10.1002/anie.200804400].

[FeFe]-hydrogenase models and hydrogen: Oxidative addition of dihydrogen and silanes

ZAMPELLA, GIUSEPPE;DE GIOIA, LUCA;
2008

Abstract

Super model: Diiron dithiolates exist in nature in [FeFe]-hydrogenase, for the purpose of making or oxidizing molecular hydrogen. Evidence for how H2 interacts with diiron complexes has been realized using model diiron dithiolato carbonyl complexes. The pathway for this interaction has been elucidated computationally as well as synthetically, by using silanes in place of H2.
Articolo in rivista - Articolo scientifico
agostic interactions, hydrogen, hydrogenase, iron, silanes
English
Heiden, Z., Zampella, G., DE GIOIA, L., & Rauchfuss, T. (2008). [FeFe]-Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 47(50), 9756-9759 [10.1002/anie.200804400].
Heiden, Z; Zampella, G; DE GIOIA, L; Rauchfuss, T
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/6095
Citazioni
  • Scopus 25
  • ???jsp.display-item.citation.isi??? 26
Social impact