We have determined the photophysical properties of [Eu(C12H8N2)2](NO3)3, (EuPhen), a complex which is very promising for photonic and optoelectronic applications, because of its easy synthetic procedure and high thermal stability (up to 300 °C) combined with large sensitization efficiency and good emission quantum yield. Available experimental absorption and emission data have been analyzed by using Judd-Ofelt analysis. Moreover, semi-empirical calculations have been used to determine the structure of the complex and to interpret the convoluted shape of the absorption spectrum. © 2009 Elsevier B.V. All rights reserved.
Scotognella, F., Meinardi, F., Ottonelli, M., Raimondo, L., Tubino, R. (2009). Photophysical analysis of the organic complex [Eu(C12H8N2)2](NO3)3. JOURNAL OF LUMINESCENCE, 129(7), 746-750 [10.1016/j.jlumin.2009.02.007].
Photophysical analysis of the organic complex [Eu(C12H8N2)2](NO3)3
MEINARDI, FRANCESCO;RAIMONDO, LUISA;TUBINO, RICCARDO
2009
Abstract
We have determined the photophysical properties of [Eu(C12H8N2)2](NO3)3, (EuPhen), a complex which is very promising for photonic and optoelectronic applications, because of its easy synthetic procedure and high thermal stability (up to 300 °C) combined with large sensitization efficiency and good emission quantum yield. Available experimental absorption and emission data have been analyzed by using Judd-Ofelt analysis. Moreover, semi-empirical calculations have been used to determine the structure of the complex and to interpret the convoluted shape of the absorption spectrum. © 2009 Elsevier B.V. All rights reserved.
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