The first crystalline microporous zirconium phosphonate metal–organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.

Taddei, M., Costantino, F., Marmottini, F., Comotti, A., Sozzani, P., Vivani, R. (2014). The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks. CHEMICAL COMMUNICATIONS, 50(94), 14831-14834 [10.1039/C4CC06223J].

The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks

COMOTTI, ANGIOLINA;SOZZANI, PIERO ERNESTO;
2014

Abstract

The first crystalline microporous zirconium phosphonate metal–organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.
Articolo in rivista - Articolo scientifico
zirconium phosphonate MOFs, permanent porosity, gas adsorption, CO2, methane
English
2014
50
94
14831
14834
none
Taddei, M., Costantino, F., Marmottini, F., Comotti, A., Sozzani, P., Vivani, R. (2014). The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks. CHEMICAL COMMUNICATIONS, 50(94), 14831-14834 [10.1039/C4CC06223J].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/58939
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