Y0.99Er0.01VO4 and Lu 0.99Er0.01VO4 zircon-type compounds have been synthesized by solid-state reaction starting from the parent oxides. The obtained materials are single phase, well crystallized and homogeneous in the chemical composition. The magic angle spinning-NMR characterization points toward the substitutional nature of erbium on the rare earth site. The isotropic chemical shift of 89Y in an orthovanadate is reported for the first time.
Amantea, R., Ghigna, P., Mustarelli, P., Tartara, V. (2005). Synthesis, 89Y and 51V-NMR of Er-doped zircon-type YVO4 and LuVO4. JOURNAL OF SOLID STATE CHEMISTRY, 178(5), 1692-1696 [10.1016/j.jssc.2005.03.014].
Synthesis, 89Y and 51V-NMR of Er-doped zircon-type YVO4 and LuVO4
Mustarelli P.;
2005
Abstract
Y0.99Er0.01VO4 and Lu 0.99Er0.01VO4 zircon-type compounds have been synthesized by solid-state reaction starting from the parent oxides. The obtained materials are single phase, well crystallized and homogeneous in the chemical composition. The magic angle spinning-NMR characterization points toward the substitutional nature of erbium on the rare earth site. The isotropic chemical shift of 89Y in an orthovanadate is reported for the first time.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.


