We present a novel strategy for the synthesis of pure and Eu-doped γ-Ga2O3 nanoparticles with an in situ organic capping resulting from a non-aqueous solution-based benzyl alcohol synthesis route. Photoluminescence spectroscopy highlights the concomitant benzoate related and γ-Ga2O3 exciton-like Eu3+ excitations in the UV, and a blue emission superimposed onto γ-Ga2O3 donor–acceptor recombination, ascribable to organic moieties different from benzoate.
Lorenzi, R., Paleari, A., Golubev, N., Ignat'Eva, E., Sigaev, V., Niederberger, M., et al. (2015). Non-aqueous sol-gel synthesis of hybrid rare-earth-doped γ-Ga2O3 nanoparticles with multiple organic-inorganic-ionic light-emission features. JOURNAL OF MATERIALS CHEMISTRY. C, 3(1), 41-45 [10.1039/c4tc02118e].
Non-aqueous sol-gel synthesis of hybrid rare-earth-doped γ-Ga2O3 nanoparticles with multiple organic-inorganic-ionic light-emission features
LORENZI, ROBERTO
;PALEARI, ALBERTO MARIA FELICESecondo
;
2015
Abstract
We present a novel strategy for the synthesis of pure and Eu-doped γ-Ga2O3 nanoparticles with an in situ organic capping resulting from a non-aqueous solution-based benzyl alcohol synthesis route. Photoluminescence spectroscopy highlights the concomitant benzoate related and γ-Ga2O3 exciton-like Eu3+ excitations in the UV, and a blue emission superimposed onto γ-Ga2O3 donor–acceptor recombination, ascribable to organic moieties different from benzoate.File | Dimensione | Formato | |
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