We demonstrate the feasibility of p-type Cu2O as a hole injection/collection layer on low-bandgap In-rich InGaN nanowires (NWs). This overcomes the difficulty of p-type doping of In-rich InGaN and the use of wide-bandgap low-In-content p-type InGaN layers. The n-type InGaN NWs with 45% In content are grown by plasma-assisted molecular beam epitaxy and the Cu2O layers on top are fabricated by electrodeposition at low temperature. The Cu2O/InGaN heterostructure is characterized by x-ray diffraction, scanning electron microscopy, energy dispersive x-ray spectroscopy, transmission electron microscopy, Raman spectroscopy, photoluminescence spectroscopy, and current-voltage measurements. For sufficient Cu2O deposition amount to form a fully coalesced, compact layer and optimized Cu2O deposition temperature of 35 °C, the current-voltage curve shows a clear rectifying behavior with a rectification ratio close to 5 at ±3 V and turn-on voltage of 1.45 V. This reveals the successful hole injection from p-type Cu2O into n-type In-rich InGaN, but the obviously still high interface state density requires further improvement.
Wang, X., Wang, P., Yin, H., Zhou, G., Notzel, R. (2020). Cu2O as hole injection layer on In-rich InGaN nanowires. JOURNAL OF APPLIED PHYSICS, 128(2) [10.1063/1.5145035].
Cu2O as hole injection layer on In-rich InGaN nanowires
Notzel R.
2020
Abstract
We demonstrate the feasibility of p-type Cu2O as a hole injection/collection layer on low-bandgap In-rich InGaN nanowires (NWs). This overcomes the difficulty of p-type doping of In-rich InGaN and the use of wide-bandgap low-In-content p-type InGaN layers. The n-type InGaN NWs with 45% In content are grown by plasma-assisted molecular beam epitaxy and the Cu2O layers on top are fabricated by electrodeposition at low temperature. The Cu2O/InGaN heterostructure is characterized by x-ray diffraction, scanning electron microscopy, energy dispersive x-ray spectroscopy, transmission electron microscopy, Raman spectroscopy, photoluminescence spectroscopy, and current-voltage measurements. For sufficient Cu2O deposition amount to form a fully coalesced, compact layer and optimized Cu2O deposition temperature of 35 °C, the current-voltage curve shows a clear rectifying behavior with a rectification ratio close to 5 at ±3 V and turn-on voltage of 1.45 V. This reveals the successful hole injection from p-type Cu2O into n-type In-rich InGaN, but the obviously still high interface state density requires further improvement.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.