A case study of the complex interplay of electrodes surface potentials and reactants oxidation potentials for photofuel cell (PFC) operation is highlighted. Cyclic voltammetry (CV) reveals that InN/InGaN quantum dots (QDs) are active for H2O2 and water oxidation in the light. InGaN nanowires (NWs) are active for H2O2 oxidation in the light and dark. In H2O2 PFC operation, high performance is achieved for InN/InGaN QDs in the light. NWs operate with lower performance in the light and dark. Similarly, with glucose as biofuel, the NWs are active in the light and dark, the QDs only in the light. All results are explained by the surface states on the c-plane QDs and m-plane NW sidewalls, the oxidation potentials of H2O2, water and glucose, and the catalytic activity of the QDs.
Qin, L., Xie, L., Chen, Y., Nötzel, R. (2022). Comparison of InN/InGaN quantum dot and nanowire hydrogen peroxide and glucose photofuel cells: A case study. CHEMICAL ENGINEERING JOURNAL ADVANCES, 11 [10.1016/j.ceja.2022.100332].
Comparison of InN/InGaN quantum dot and nanowire hydrogen peroxide and glucose photofuel cells: A case study
Nötzel R.
2022
Abstract
A case study of the complex interplay of electrodes surface potentials and reactants oxidation potentials for photofuel cell (PFC) operation is highlighted. Cyclic voltammetry (CV) reveals that InN/InGaN quantum dots (QDs) are active for H2O2 and water oxidation in the light. InGaN nanowires (NWs) are active for H2O2 oxidation in the light and dark. In H2O2 PFC operation, high performance is achieved for InN/InGaN QDs in the light. NWs operate with lower performance in the light and dark. Similarly, with glucose as biofuel, the NWs are active in the light and dark, the QDs only in the light. All results are explained by the surface states on the c-plane QDs and m-plane NW sidewalls, the oxidation potentials of H2O2, water and glucose, and the catalytic activity of the QDs.
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