Tactoids are pointed, spindlelike droplets of nematic liquid crystal in an isotropic fluid. They have long been observed in inorganic and organic nematics, in thermotropic phases as well as lyotropic colloidal aggregates. The variational problem of determining the optimal shape of a nematic droplet is formidable and has only been attacked in selected classes of shapes and director fields. Here, by considering a special class of admissible solutions for a bipolar droplet, we study the prevalence in the population of all equilibrium shapes of each of the three that may be optimal (tactoids primarily among them). We show how the prevalence of a shape is affected by a dimensionless measure a of the drop's volume and the ratios k(24) and k(3) of the saddle-splay constant K-24 and the bending constant K-33 of the material to the splay constant K-11. Tactoids, in particular, prevail for alpha (sic) 16.2 + 0.3k(3) - (14.9 - 0.1k(3))k(24). Our class of shapes (and director fields) is sufficiently different from those employed so far to unveil a rather different role of K-24.

Paparini, S., Virga, E. (2021). Nematic tactoid population. PHYSICAL REVIEW. E, 103(2), 1-18 [10.1103/PhysRevE.103.022707].

Nematic tactoid population

Paparini, S;Virga, EG
2021

Abstract

Tactoids are pointed, spindlelike droplets of nematic liquid crystal in an isotropic fluid. They have long been observed in inorganic and organic nematics, in thermotropic phases as well as lyotropic colloidal aggregates. The variational problem of determining the optimal shape of a nematic droplet is formidable and has only been attacked in selected classes of shapes and director fields. Here, by considering a special class of admissible solutions for a bipolar droplet, we study the prevalence in the population of all equilibrium shapes of each of the three that may be optimal (tactoids primarily among them). We show how the prevalence of a shape is affected by a dimensionless measure a of the drop's volume and the ratios k(24) and k(3) of the saddle-splay constant K-24 and the bending constant K-33 of the material to the splay constant K-11. Tactoids, in particular, prevail for alpha (sic) 16.2 + 0.3k(3) - (14.9 - 0.1k(3))k(24). Our class of shapes (and director fields) is sufficiently different from those employed so far to unveil a rather different role of K-24.
Articolo in rivista - Articolo scientifico
Nematic liquid crystals; Sols
English
2021
103
2
1
18
022707
none
Paparini, S., Virga, E. (2021). Nematic tactoid population. PHYSICAL REVIEW. E, 103(2), 1-18 [10.1103/PhysRevE.103.022707].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/518240
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