Cu(II) triflate reacts with 4,4 -bipyridyl in different solvents to yield the new 3D network [Cu(4,4-bipy)(2)(CF3SO3)(2)], based on pseudo-square planar nodes and consisting of crossing layers of large rhombic meshes (22 x 22 Angstrom) fused together into an overall (two-fold interpenetrated) array, with a topology unprecedented within coordination frames and an interesting nanoporous behaviour.

Carlucci, L., Cozzi, N., Ciani, G., Moret, M., Proserpio, D., Rizzato, S. (2002). A three-dimensional nanoporous flexible network of 'square-planar' copper(ii) centres with an unusual topology. CHEMICAL COMMUNICATIONS, 2002(13), 1354-1355 [10.1039/b202588d].

A three-dimensional nanoporous flexible network of 'square-planar' copper(ii) centres with an unusual topology

MORET, MASSIMO;
2002

Abstract

Cu(II) triflate reacts with 4,4 -bipyridyl in different solvents to yield the new 3D network [Cu(4,4-bipy)(2)(CF3SO3)(2)], based on pseudo-square planar nodes and consisting of crossing layers of large rhombic meshes (22 x 22 Angstrom) fused together into an overall (two-fold interpenetrated) array, with a topology unprecedented within coordination frames and an interesting nanoporous behaviour.
Articolo in rivista - Articolo scientifico
MOF; microporous solid; copper; structure
English
2002
2002
13
1354
1355
none
Carlucci, L., Cozzi, N., Ciani, G., Moret, M., Proserpio, D., Rizzato, S. (2002). A three-dimensional nanoporous flexible network of 'square-planar' copper(ii) centres with an unusual topology. CHEMICAL COMMUNICATIONS, 2002(13), 1354-1355 [10.1039/b202588d].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/5130
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