Substitution of the acetonitrile ligands in Fe4Cu2C(CO)12- (MeCN)2 with bidentate L–L ligands, such as 4,4¢-bipyridine (bipy), pyrazine (pyz) or p-dicyanobenzene (p-DCB), gives rise to either infinite [Fe4Cu2(l6-C)(CO)12(l-L–L)]• zigzag chain polymers or to [Fe4Cu2(l6-C)(CO)12(l-L–L)]4·8THF square oligomers, as a function of the crystallization solvent.
Femoni, C., Della Pergola, R., Iapalucci, M.C., Kaswalder, F., Riccò, M., & Zacchini, S. (2009). Copolymerization of Fe4Cu2C(CO)12 Moieties with Bidentate N-Ligands: Synthesis and Crystal Structure of the [Fe4Cu2(μ6-C)(CO)12(μ-bipy)]4•2THF Square Tetramer and the Infinite [Fe4Cu2(μ6-C)(CO)12(μ-L-L)]∞ Zigzag Chains. DALTON TRANSACTIONS, 2009(9), 1509-1511.
Citazione: | Femoni, C., Della Pergola, R., Iapalucci, M.C., Kaswalder, F., Riccò, M., & Zacchini, S. (2009). Copolymerization of Fe4Cu2C(CO)12 Moieties with Bidentate N-Ligands: Synthesis and Crystal Structure of the [Fe4Cu2(μ6-C)(CO)12(μ-bipy)]4•2THF Square Tetramer and the Infinite [Fe4Cu2(μ6-C)(CO)12(μ-L-L)]∞ Zigzag Chains. DALTON TRANSACTIONS, 2009(9), 1509-1511. |
Tipo: | Articolo in rivista - Articolo scientifico |
Carattere della pubblicazione: | Scientifica |
Titolo: | Copolymerization of Fe4Cu2C(CO)12 Moieties with Bidentate N-Ligands: Synthesis and Crystal Structure of the [Fe4Cu2(μ6-C)(CO)12(μ-bipy)]4•2THF Square Tetramer and the Infinite [Fe4Cu2(μ6-C)(CO)12(μ-L-L)]∞ Zigzag Chains |
Autori: | Femoni, C; Della Pergola, R; Iapalucci, MC; Kaswalder, F; Riccò, M; Zacchini, S |
Autori: | |
Data di pubblicazione: | 2009 |
Lingua: | English |
Rivista: | DALTON TRANSACTIONS |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/b821639h |
Appare nelle tipologie: | 01 - Articolo su rivista |