Currently, the scientific community has spent a lot of effort in developing “green” and environmentally friendly processes and products, due the contemporary problems connected to pollution and climate change. Cellulose nanocrystals (CNCs) are at the forefront of current research due to their multifunctional characteristics of biocompatibility, high mechanical properties, specific surface area, tunable surface chemistry and renewability. However, despite these many advantages, their inherent hydrophilicity poses a substantial challenge for the application of CNCs as a reinforcing filler in polymers, as it complicates their dispersion in hydrophobic polymeric matrices, such as polyurethane foams, often resulting in aggregate structures that compromise their properties. The manipulation and fine-tuning of the interfacial properties of CNCs is a crucial step to exploit their full potential in the development of new materials. In this respect, starting from an aqueous dispersion of CNCs, two different strategies were used to properly functionalize fillers: (i) freeze drying, solubilization in DMA/LiCl media and subsequent grafting with bio-based polyols; (ii) solvent exchange and subsequent grafting with bio-based polyols. The influence of the two functionalization methods on the chemical and thermal properties of CNCs was examined. In both cases, the role of the two bio-based polyols on filler functionalization was elucidated. Afterwards, the functionalized CNCs were used at 5 wt% to produce bio-based composite polyurethane foams and their effect on the morphological, thermal and mechanical properties was examined. It was found that CNCs modified through freeze drying, solubilization and bio-polyols grafting exhibited remarkably higher thermal stability (i.e., degradation stages > 100 °C) with respect to the unmodified freeze dried-CNCs. In addition, the use of the two grafting bio-polyols influenced the functionalization process, corresponding to different amount of grafted-silane-polyol and leading to different chemico-physical characteristics of the obtained CNCs. This was translated to higher thermal stability as well as improved functional and mechanical performances of the produced bio-based composite PUR foams with respect of the unmodified CNCs-composite ones (the best case attained compressive strength values three times more). Solvent exchange route slightly improved the thermal stability of the obtained CNCs; however; the so-obtained CNCs could not be properly dispersed within the polyurethane matrix, due to filler aggregation.

Fontana, D., Recupido, F., Lama, G., Liu, J., Boggioni, L., Silvano, S., et al. (2023). Effect of Different Methods to Synthesize Polyol-Grafted-Cellulose Nanocrystals as Inter-Active Filler in Bio-Based Polyurethane Foams. POLYMERS, 15(4) [10.3390/polym15040923].

Effect of Different Methods to Synthesize Polyol-Grafted-Cellulose Nanocrystals as Inter-Active Filler in Bio-Based Polyurethane Foams

Silvano S.;
2023

Abstract

Currently, the scientific community has spent a lot of effort in developing “green” and environmentally friendly processes and products, due the contemporary problems connected to pollution and climate change. Cellulose nanocrystals (CNCs) are at the forefront of current research due to their multifunctional characteristics of biocompatibility, high mechanical properties, specific surface area, tunable surface chemistry and renewability. However, despite these many advantages, their inherent hydrophilicity poses a substantial challenge for the application of CNCs as a reinforcing filler in polymers, as it complicates their dispersion in hydrophobic polymeric matrices, such as polyurethane foams, often resulting in aggregate structures that compromise their properties. The manipulation and fine-tuning of the interfacial properties of CNCs is a crucial step to exploit their full potential in the development of new materials. In this respect, starting from an aqueous dispersion of CNCs, two different strategies were used to properly functionalize fillers: (i) freeze drying, solubilization in DMA/LiCl media and subsequent grafting with bio-based polyols; (ii) solvent exchange and subsequent grafting with bio-based polyols. The influence of the two functionalization methods on the chemical and thermal properties of CNCs was examined. In both cases, the role of the two bio-based polyols on filler functionalization was elucidated. Afterwards, the functionalized CNCs were used at 5 wt% to produce bio-based composite polyurethane foams and their effect on the morphological, thermal and mechanical properties was examined. It was found that CNCs modified through freeze drying, solubilization and bio-polyols grafting exhibited remarkably higher thermal stability (i.e., degradation stages > 100 °C) with respect to the unmodified freeze dried-CNCs. In addition, the use of the two grafting bio-polyols influenced the functionalization process, corresponding to different amount of grafted-silane-polyol and leading to different chemico-physical characteristics of the obtained CNCs. This was translated to higher thermal stability as well as improved functional and mechanical performances of the produced bio-based composite PUR foams with respect of the unmodified CNCs-composite ones (the best case attained compressive strength values three times more). Solvent exchange route slightly improved the thermal stability of the obtained CNCs; however; the so-obtained CNCs could not be properly dispersed within the polyurethane matrix, due to filler aggregation.
Articolo in rivista - Articolo scientifico
bio-based polyurethane composite foams; CNC dispersion functionalization; CNC solvent exchange-functionalization; CNCs; natural fillers;
English
12-feb-2023
2023
15
4
923
open
Fontana, D., Recupido, F., Lama, G., Liu, J., Boggioni, L., Silvano, S., et al. (2023). Effect of Different Methods to Synthesize Polyol-Grafted-Cellulose Nanocrystals as Inter-Active Filler in Bio-Based Polyurethane Foams. POLYMERS, 15(4) [10.3390/polym15040923].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/495779
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