The steady-state absorption and fluorescence, as well as the time-resolved fluorescence properties of dimethoxycurcumin and bis-dehydroxycurcumin dissolved in several solvents differing in polarity and H-bonding capability are presented. The singlet oxygen generation efficiency of the two compounds relative to curcumin is estimated. The photodegradation quantum yield of the former compound in acetonitrile and methanol is determined. The dimethoxycurcumin and bis-dehydroxycurcumin decay mechanisms from the S1 state are discussed and compared with those of curcumin, dicinnamoylmethane and bis-demethoxycurcumin. © Springer Science+Business Media, LLC 2011.

Nardo, L., Andreoni, A., Bondani, M., Masson, M., Haukvik, T., Tonnesen, H. (2012). Studies on Curcumin and Curcuminoids. XLVI. Photophysical Properties of Dimethoxycurcumin and Bis-dehydroxycurcumin. JOURNAL OF FLUORESCENCE, 22(2), 597-608 [10.1007/s10895-011-0995-z].

Studies on Curcumin and Curcuminoids. XLVI. Photophysical Properties of Dimethoxycurcumin and Bis-dehydroxycurcumin

NARDO, LUCA;
2012

Abstract

The steady-state absorption and fluorescence, as well as the time-resolved fluorescence properties of dimethoxycurcumin and bis-dehydroxycurcumin dissolved in several solvents differing in polarity and H-bonding capability are presented. The singlet oxygen generation efficiency of the two compounds relative to curcumin is estimated. The photodegradation quantum yield of the former compound in acetonitrile and methanol is determined. The dimethoxycurcumin and bis-dehydroxycurcumin decay mechanisms from the S1 state are discussed and compared with those of curcumin, dicinnamoylmethane and bis-demethoxycurcumin. © Springer Science+Business Media, LLC 2011.
Articolo in rivista - Articolo scientifico
curcuminoids; excited-state intramolecular proton transfer; excited-state dynamics; solute-solvent interactions
English
2012
22
2
597
608
none
Nardo, L., Andreoni, A., Bondani, M., Masson, M., Haukvik, T., Tonnesen, H. (2012). Studies on Curcumin and Curcuminoids. XLVI. Photophysical Properties of Dimethoxycurcumin and Bis-dehydroxycurcumin. JOURNAL OF FLUORESCENCE, 22(2), 597-608 [10.1007/s10895-011-0995-z].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/49103
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