The development of photoresponsive systems with non-invasive orthogonal control by distinct wavelengths of light is still in its infancy. In particular, the design of photochemically triggered-orthogonal systems integrated into solid materials that enable multiple dynamic control over their properties remains a longstanding challenge. Here, we report the orthogonal and reversible control of two types of photoswitches in an integrated solid porous framework, that is, visible-light responsive o-fluoroazobenzene and nitro-spiropyran motifs. The properties of the constructed material can be selectively controlled by different wavelengths of light thus generating four distinct states providing a basis for dynamic multifunctional materials. Solid-state NMR spectroscopy demonstrated the selective transformation of the azobenzene switch in the bulk, which in turn modulates N2 and CO2 adsorption.

Sheng, J., Perego, J., Bracco, S., Cieciórski, P., Danowski, W., Comotti, A., et al. (2024). Orthogonal Photoswitching in a Porous Organic Framework. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 1-8 [10.1002/anie.202404878].

Orthogonal Photoswitching in a Porous Organic Framework

Perego J.;Bracco S.;Comotti A.
;
2024

Abstract

The development of photoresponsive systems with non-invasive orthogonal control by distinct wavelengths of light is still in its infancy. In particular, the design of photochemically triggered-orthogonal systems integrated into solid materials that enable multiple dynamic control over their properties remains a longstanding challenge. Here, we report the orthogonal and reversible control of two types of photoswitches in an integrated solid porous framework, that is, visible-light responsive o-fluoroazobenzene and nitro-spiropyran motifs. The properties of the constructed material can be selectively controlled by different wavelengths of light thus generating four distinct states providing a basis for dynamic multifunctional materials. Solid-state NMR spectroscopy demonstrated the selective transformation of the azobenzene switch in the bulk, which in turn modulates N2 and CO2 adsorption.
Articolo in rivista - Articolo scientifico
Azobenzene; Molecular switch; Orthogonal photoswitching; Solid-state isomerization; Spiropyran;
English
26-mar-2024
2024
1
8
e202404878
open
Sheng, J., Perego, J., Bracco, S., Cieciórski, P., Danowski, W., Comotti, A., et al. (2024). Orthogonal Photoswitching in a Porous Organic Framework. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 1-8 [10.1002/anie.202404878].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/478339
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