Basin-scale transfer of nitrate pollution from groundwater to surface water in an intensively irrigated system

Basin-scale studies addressing the transfer of pollutants among groundwater and surface water bodies are essential to support local authorities in the sustainable management of freshwater resources. This work revealed that, in the hydro-system of the Oglio River basin (Northern Italy), nitrate pollution in groundwater, originated by overfertilization, is trans- ferred downstream to surface water bodies via outflow through lowland springs and base- flow to gaining rivers. Downstream groundwater is unaffected due to reducing conditions that facilitate denitrification. It follows that efficient measures to reduce nitrate pollution in surface water bodies should not be applied solely to rivers/streams but, instead, they should include the upstream groundwater body. The work aimed at understanding nitrate pollution dynamics in an intensively irrigated hydro-system, focusing on the role played by the com- plex interaction among irrigation water, surface water and groundwater. The study relied on nitrate concentration, Cl/Br ratio, stable isotopic composition of water, nitrate and boron in groundwater, river, lake, spring, and rainwater samples. Results highlighted a well-defined spatial distribution of nitrate concentrations in groundwater, mainly driven by irrigation practices: (1) where groundwater-fed irrigation is done, return flow promotes high nitrate concentrations (>50 mg/L) due to groundwater recirculation; (2) where intensive surface-wa- ter-irrigation is practised, fed by low-nitrate river water, return flow generates lower nitrate concentrations (<50 mg/L) due to dilution. This work highlighted the importance of a holistic approach jointly investigating surface water, groundwater, and irrigation water when nitrate pollution is examined at a basin scale.