The site-directed generation of a heterodinuclear Fe IIICu II complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Heims, F., Mereacre, V., Ciancetta, A., Mebs, S., Powell, A., Greco, C., et al. (2012). Synthesis and spectroscopic characterisation of a heterodinuclear iron(III)-copper(II) complex based on an asymmetric dinucleating ligand system. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012(29), 4565-4569 [10.1002/ejic.201200156].

Synthesis and spectroscopic characterisation of a heterodinuclear iron(III)-copper(II) complex based on an asymmetric dinucleating ligand system

GRECO, CLAUDIO;
2012

Abstract

The site-directed generation of a heterodinuclear Fe IIICu II complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Articolo in rivista - Articolo scientifico
Asymmetric Dinucleating Ligand System
English
2012
2012
29
4565
4569
none
Heims, F., Mereacre, V., Ciancetta, A., Mebs, S., Powell, A., Greco, C., et al. (2012). Synthesis and spectroscopic characterisation of a heterodinuclear iron(III)-copper(II) complex based on an asymmetric dinucleating ligand system. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012(29), 4565-4569 [10.1002/ejic.201200156].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/45825
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