Nitrogen doped titanium dioxide is attracting a continuously increasing attention because of its potential as material for environmental photocatalysis. In this paper we review experimental and theoretical work done on this system in our groups in recent years. The analysis is largely based on electron paramagnetic resonance (EPR) spectra and on their interpretation based on high-level ab initio calculations. N-doped anatase TiO2 contains thermally stable single N-atom impurities either as charged diamagnetic N-b(-) centers or as neutral paramagnetic N-b(.) centers (b stays for bulk). The N-atoms can occupy both interstitial or substitutional positions in the solid, with some evidence for a preference for interstitial sites. All types of N-b centers give rise to localized states in the band-gap of the oxide, thus accounting for the related reduction of absorption band edge. The relative abundance of these species depends on the oxidation state of the solid. In fact, upon reduction, oxygen vacancies form and transfer electrons from Ti3+ ions to the N-b(.) with formation of Ti4+ and N-b(.). EPR spectra measured under irradiation show that the Nb centers are responsible for visible light absorption with promotion of electrons from the localized N-impurity states to the conduction band or to electron scavengers like O-2 adsorbed on the surface. These results provide an unambiguous characterization of the electronic states associated with N-impurities in TiO2 and a realistic picture of the processes occurring in the solid under irradiation with visible light.
Di Valentin, C., Finazzi, E., Pacchioni, G., Selloni, A., Livraghi, S., Paganini, M., et al. (2007). N-doped TiO2: Theory and experiment. CHEMICAL PHYSICS, 339(1-3), 44-56 [10.1016/j.chemphys.2007.07.020].
|Citazione:||Di Valentin, C., Finazzi, E., Pacchioni, G., Selloni, A., Livraghi, S., Paganini, M., et al. (2007). N-doped TiO2: Theory and experiment. CHEMICAL PHYSICS, 339(1-3), 44-56 [10.1016/j.chemphys.2007.07.020].|
|Tipo:||Articolo in rivista - Articolo scientifico|
|Carattere della pubblicazione:||Scientifica|
|Titolo:||N-doped TiO2: Theory and experiment|
|Autori:||Di Valentin, C; Finazzi, E; Pacchioni, G; Selloni, A; Livraghi, S; Paganini, M; Giamello, E|
|Data di pubblicazione:||2007|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.chemphys.2007.07.020|
|Appare nelle tipologie:||01 - Articolo su rivista|