Here, the development of highly porous colorimetric indicators that are able to rapidly sense the presence of amine vapors is presented. Specifically, porous, curcumin-loaded polycaprolactone fibers are formed by electrospinning through non-solvent-induced phase separation. In comparison to the non-porous fibers, the developed system shows significantly higher sensitivity and responsivity to the presence of dimethylamine vapors, with a distinct color change at very low vapor concentrations (2.33 ppm compared to 9.26 ppm) within the first 5 s of exposure. Indeed, CIELAB analysis proves that the induced color changes can be easily perceived visually, as the differences between the initial and the final color of the indicator after its interaction with the modified environment are well above the limit for visual perception, even by inexperienced users. Furthermore, the color changes are reversible, enabling the use of the same indicator several times, making it, thus, a sustainable colorimetric indicator system that can be used in applications where the rapid detection of low concentration of alkaline vapors is necessary.

Kossyvaki, D., Barbetta, A., Contardi, M., Bustreo, M., Dziza, K., Lauciello, S., et al. (2022). Highly Porous Curcumin-Loaded Polymer Mats for Rapid Detection of Volatile Amines. ACS APPLIED POLYMER MATERIALS, 4(6), 4464-4475 [10.1021/acsapm.2c00418].

Highly Porous Curcumin-Loaded Polymer Mats for Rapid Detection of Volatile Amines

Contardi M.;
2022

Abstract

Here, the development of highly porous colorimetric indicators that are able to rapidly sense the presence of amine vapors is presented. Specifically, porous, curcumin-loaded polycaprolactone fibers are formed by electrospinning through non-solvent-induced phase separation. In comparison to the non-porous fibers, the developed system shows significantly higher sensitivity and responsivity to the presence of dimethylamine vapors, with a distinct color change at very low vapor concentrations (2.33 ppm compared to 9.26 ppm) within the first 5 s of exposure. Indeed, CIELAB analysis proves that the induced color changes can be easily perceived visually, as the differences between the initial and the final color of the indicator after its interaction with the modified environment are well above the limit for visual perception, even by inexperienced users. Furthermore, the color changes are reversible, enabling the use of the same indicator several times, making it, thus, a sustainable colorimetric indicator system that can be used in applications where the rapid detection of low concentration of alkaline vapors is necessary.
Articolo in rivista - Articolo scientifico
dimethylamine; gas sensing; intelligent packaging; pH indicators; porous electrospun fibers;
English
19-mag-2022
2022
4
6
4464
4475
open
Kossyvaki, D., Barbetta, A., Contardi, M., Bustreo, M., Dziza, K., Lauciello, S., et al. (2022). Highly Porous Curcumin-Loaded Polymer Mats for Rapid Detection of Volatile Amines. ACS APPLIED POLYMER MATERIALS, 4(6), 4464-4475 [10.1021/acsapm.2c00418].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/431919
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