Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection

The search for efficient, re-absorption-free scintillators has recently focused the attention on antimony-based halides, which exhibit largely Stokes shifted luminescence due to radiative recombination of excitons self-trapped (STE) in strongly Jahn–Teller distorted Sb3+ color centers. Here, the synthesis of a hybrid structure is reported with chemical formula (C13H14N3)3SbCl6 consisting of spatially isolated [SbCl6]3− octahedra separated by organic N,N'-diphenylguanidinium (Gua) molecules. The optical properties of this material are mainly determined by the inorganic component and are characterized by a pronounced Stokes shift of ≈1.3 eV and a room-temperature photoluminescence (PL) efficiency of up to 85%. Remarkably, highly efficient radioluminescence (RL) is observed with scintillation light yields of ≈2000 ph MeV−1 using both soft X-rays and a 124 keV gamma source. Temperature-dependent PL and RL measurements confirm the minor role of non-radiative channels, which are completely suppressed below 100 K. Thermally stimulated luminescence measurements suggest that the traps in Gua3SbCl6 crystals have a significantly large energy depth distribution below the absorbing state.