Novel 2-D materials for tunneling FETs: An Ab-initio Study

An excellent electrostatic control has been early on identified as one of the most critical ingredients to build band- to- band tunneling field-effect transistors (TFETs) with a steep sub-threshold swing (SS) and a high ON-current (ION) [1]. These essential features can be obtained by reducing the thickness of ultra-thin-body structures or the diameter of nanowires. Two-dimensional materials, especially their single-layer (SL) configuration, represent a promising alternative to conventional semiconductors due to their intrinsic sub-1nm thickness. Indeed, a TFET implementing an atomically thin MoS2 channel combined with a Ge layer was recently shown to exhibit a less than 60 mV/dec SS over several orders of magnitude and a decent ION[2]. In this experiment, however, MoS2 had to be grouped with Ge to achieve the desired goal, thus raising the question whether 2-D materials alone can provide a suitable platform for high performance TFETs. Various theoretical studies based on empirical tight-binding models and focusing on SL transition metal dichalcogenides (TMDs) [3] and black phosphorus [4] have come to the conclusion that these compounds, in particular WTe2, could deliver ON-currents larger than 100μ A/μ m at a supply voltage VDD=0.5V and OFF-current IOFF=1nA/μm. Here, by employing an ab-initio quantum transport simulator, we will demonstrate that none of the usual TMDs reaches a ION > > 10μ A/μm, contrary to recently discovered 2-D materials [5] that could pave the way for future, highly efficient TFETs.