Metallacycles of increasing size were obtained by reaction of octahedral Fe/Cu/C clusters and anionic ligands, with different donor atoms (O, N, S). They were characterized by X-ray determination IR, 1H-NMR and electrochemical studies. The carbidocarbonyl clusters are stable upon electron transfer and the bridging ligand allow electronic communication.
DELLA PERGOLA, R., Sironi, A., Moret, M., Bergantin, S., Mussini, P., Panigati, M. (2013). Cyclic dimers of variable size, formed from FeCu carbide clusters: synthesis, structure and electrochemical behaviour of [{Fe4C(CO)12Cu2(μ-X)}2]n-, (X = phenylthiolate, pyrazolate, (n = 2) or diphenolate (n = 4)). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 728, 23-29 [10.1016/j.jorganchem.2013.01.006].
Cyclic dimers of variable size, formed from FeCu carbide clusters: synthesis, structure and electrochemical behaviour of [{Fe4C(CO)12Cu2(μ-X)}2]n-, (X = phenylthiolate, pyrazolate, (n = 2) or diphenolate (n = 4))
DELLA PERGOLA, ROBERTO;SIRONI, ANNALISA;MORET, MASSIMO;BERGANTIN, STEFANO;
2013
Abstract
Metallacycles of increasing size were obtained by reaction of octahedral Fe/Cu/C clusters and anionic ligands, with different donor atoms (O, N, S). They were characterized by X-ray determination IR, 1H-NMR and electrochemical studies. The carbidocarbonyl clusters are stable upon electron transfer and the bridging ligand allow electronic communication.
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