A [copper(I)pyridine-containing ligand]-catalyzed reaction between 2-vinylindoles and diazo esters is described. The reaction allows for the synthesis of a series of 2-vinylcyclopropa[b]indolines with excellent levels of regio- and sterocontrol under mild conditions.

Pirovano, V., Brambilla, E., Tseberlidis, G. (2018). [Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2-Vinylcyclopropa[b]indolines from 2-Vinylindoles. ORGANIC LETTERS, 20(2), 405-408 [10.1021/acs.orglett.7b03704].

[Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2-Vinylcyclopropa[b]indolines from 2-Vinylindoles

Tseberlidis, G
2018

Abstract

A [copper(I)pyridine-containing ligand]-catalyzed reaction between 2-vinylindoles and diazo esters is described. The reaction allows for the synthesis of a series of 2-vinylcyclopropa[b]indolines with excellent levels of regio- and sterocontrol under mild conditions.
Articolo in rivista - Articolo scientifico
Asymmetric cyclopropanation; stereoselective-synthesis; ethyl diazoacetate; CU(I) complexes; enantioselective synthesis; copper; indoles; heterocycles; derivatives; SILICA
English
405
408
4
Pirovano, V., Brambilla, E., Tseberlidis, G. (2018). [Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2-Vinylcyclopropa[b]indolines from 2-Vinylindoles. ORGANIC LETTERS, 20(2), 405-408 [10.1021/acs.orglett.7b03704].
Pirovano, V; Brambilla, E; Tseberlidis, G
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/396501
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