The Cu4 derivatives of [EtSiO2]Na have been synthesised and their cyclic voltammetry, spectroscopic behaviour and X-ray structure determination described. The changes in the alkali cation, Na+ in place of K+, might have a 'tuning' effect in the organisation on the siloxanolate clusters resulting in a macrocyclic ([EtSiO2]12) ligand instead of two cyclic ([EtSiO2]6) ligands.

Zucchi, C., Mattioli, M., Gavioli, G., Moret, M., Sironi, A., Ugo, R., et al. (2000). Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect?. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(6), 1327-1331 [10.1002/(SICI)1099-0682(200006)2000:6<1327::AID-EJIC1327>3.0.CO;2-V].

Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect?

MORET, MASSIMO;
2000

Abstract

The Cu4 derivatives of [EtSiO2]Na have been synthesised and their cyclic voltammetry, spectroscopic behaviour and X-ray structure determination described. The changes in the alkali cation, Na+ in place of K+, might have a 'tuning' effect in the organisation on the siloxanolate clusters resulting in a macrocyclic ([EtSiO2]12) ligand instead of two cyclic ([EtSiO2]6) ligands.
Articolo in rivista - Articolo scientifico
Alkali metals; Cations; Cluster compounds; Cyclooligomerizations; Si ligands;
English
2000
6
1327
1331
none
Zucchi, C., Mattioli, M., Gavioli, G., Moret, M., Sironi, A., Ugo, R., et al. (2000). Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect?. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(6), 1327-1331 [10.1002/(SICI)1099-0682(200006)2000:6<1327::AID-EJIC1327>3.0.CO;2-V].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/37882
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