Reaction of Fe-3(CO)(12) with pyridinyl thioester ligand PyCH2SCOCH3 (L-1, Py = pyridin-2-yl) produced complex, [Fe-2(kappa-COCH3)(mu-SCH2Py)(CO)(5)] (1) (PyCH2S = pyridin-2-ylmethanethiolate). When complex 1 reacted with PPh3, a monosubstituted complex, [Fe-2(kappa-COCH3)(mu-SCH2Py)(CO)(4)PPh3] (2), was derived. Reaction of the same precursor with analogous thioester ligand PyCH2SCOPy (L-2) generated three novel diiron complexes, [Fe-2(kappa-Py)(mu-SCH2Py)(CO)(5)] (3), [Fe-2(kappa-Py)'(mu-SCH2Py)(CO)(5)] (4), and [Fe-2(kappa-Py)(mu-SCH2Py)(CO)(6)] (5). Complexes 3 and 4 are structural isomers. Complex 5 could be converted into complex 4 but the conversion from complex 5 to the isomer 3 was not observed. All the five complexes were fully characterised using FTIR, NMR, and other techniques. Their structures were determined using X-ray single crystal diffraction analysis. The oxidative formation of complexes 1, 3, 4, and 5 involved C-S and/ or C-C bonds cleavages. To probe possible mechanisms for these cleavages, DFT calculations were performed. From the calculations, viable reaction pathways leading to the formation of all the isolated products were delineated. The results of the theoretic calculations also allowed rationalisation of the experimental observations.

Long, L., Xiao, Z., Zampella, G., Wei, Z., DE GIOIA, L., Liu, X. (2012). The reactions of pyridinyl thioesters with triiron dodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations. DALTON TRANSACTIONS, 41(31), 9482-9492 [10.1039/C2DT30798G].

The reactions of pyridinyl thioesters with triiron dodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations

ZAMPELLA, GIUSEPPE;DE GIOIA, LUCA;
2012

Abstract

Reaction of Fe-3(CO)(12) with pyridinyl thioester ligand PyCH2SCOCH3 (L-1, Py = pyridin-2-yl) produced complex, [Fe-2(kappa-COCH3)(mu-SCH2Py)(CO)(5)] (1) (PyCH2S = pyridin-2-ylmethanethiolate). When complex 1 reacted with PPh3, a monosubstituted complex, [Fe-2(kappa-COCH3)(mu-SCH2Py)(CO)(4)PPh3] (2), was derived. Reaction of the same precursor with analogous thioester ligand PyCH2SCOPy (L-2) generated three novel diiron complexes, [Fe-2(kappa-Py)(mu-SCH2Py)(CO)(5)] (3), [Fe-2(kappa-Py)'(mu-SCH2Py)(CO)(5)] (4), and [Fe-2(kappa-Py)(mu-SCH2Py)(CO)(6)] (5). Complexes 3 and 4 are structural isomers. Complex 5 could be converted into complex 4 but the conversion from complex 5 to the isomer 3 was not observed. All the five complexes were fully characterised using FTIR, NMR, and other techniques. Their structures were determined using X-ray single crystal diffraction analysis. The oxidative formation of complexes 1, 3, 4, and 5 involved C-S and/ or C-C bonds cleavages. To probe possible mechanisms for these cleavages, DFT calculations were performed. From the calculations, viable reaction pathways leading to the formation of all the isolated products were delineated. The results of the theoretic calculations also allowed rationalisation of the experimental observations.
Articolo in rivista - Articolo scientifico
CLUSTER-FREE HYDROGENASE; IRON-ONLY HYDROGENASE; ACTIVE-SITE; CRYSTAL-STRUCTURE; 3RD HYDROGENASE; MODEL COMPLEXES; FE HYDROGENASES; H-2 ACTIVATION; HMD; REACTIVITY
English
2012
41
31
9482
9492
none
Long, L., Xiao, Z., Zampella, G., Wei, Z., DE GIOIA, L., Liu, X. (2012). The reactions of pyridinyl thioesters with triiron dodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations. DALTON TRANSACTIONS, 41(31), 9482-9492 [10.1039/C2DT30798G].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/37185
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