Interpenetrated nanocomposites were formed by polymerization of acrylonitrile in a ultrahigh surface area (>5000 m2 g−1) porous framework. The resulting material realizes a hyperextended interface with uniform interdigitation of the two structures at the size limit of the individual molecular moieties. The confined poly(acrylonitrile) chains could be transformed into light-absorbing polyconjugated ladder polymers.

Comotti, A., Bracco, S., Mauri, M., Mottadelli, S., Ben, T., Qiu, S., et al. (2012). Confined Polymerization in Porous Organic Frameworks with an Ultrahigh Surface Area. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51(40), 10136-10140 [10.1002/anie.201205618].

Confined Polymerization in Porous Organic Frameworks with an Ultrahigh Surface Area

COMOTTI, ANGIOLINA
;
BRACCO, SILVIA;MAURI, MARTINO;SOZZANI, PIERO ERNESTO
2012

Abstract

Interpenetrated nanocomposites were formed by polymerization of acrylonitrile in a ultrahigh surface area (>5000 m2 g−1) porous framework. The resulting material realizes a hyperextended interface with uniform interdigitation of the two structures at the size limit of the individual molecular moieties. The confined poly(acrylonitrile) chains could be transformed into light-absorbing polyconjugated ladder polymers.
Articolo in rivista - Articolo scientifico
host–guest systems; ladder polymers; microporous materials; nanostructures; polymerization; solid state NMR
English
2012
51
40
10136
10140
none
Comotti, A., Bracco, S., Mauri, M., Mottadelli, S., Ben, T., Qiu, S., et al. (2012). Confined Polymerization in Porous Organic Frameworks with an Ultrahigh Surface Area. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51(40), 10136-10140 [10.1002/anie.201205618].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/36648
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