Dipeptide crystals have been used for solid-state polymerization reactions. The porosity of the crystals enables monomer absorption, followed by γ-irradiation to produce polymers with high molecular weights. The crystal channels induce stereoselective reactions to yield 1,4-trans polydienes and isotactic poly(acrylonitrile) with retention of fibrillar morphology

Distefano, G., Comotti, A., Bracco, S., Beretta, M., Sozzani, P. (2012). Porous Dipeptide Crystals as Polymerization Nanoreactors. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51(37), 9258-9262 [10.1002/anie.201204178].

Porous Dipeptide Crystals as Polymerization Nanoreactors

DISTEFANO, GAETANO;COMOTTI, ANGIOLINA;BRACCO, SILVIA;BERETTA, MARIO;SOZZANI, PIERO ERNESTO
2012

Abstract

Dipeptide crystals have been used for solid-state polymerization reactions. The porosity of the crystals enables monomer absorption, followed by γ-irradiation to produce polymers with high molecular weights. The crystal channels induce stereoselective reactions to yield 1,4-trans polydienes and isotactic poly(acrylonitrile) with retention of fibrillar morphology
Articolo in rivista - Articolo scientifico
crystal engineering; microporous materials; peptides; polymerization; topochemistry
English
2012
51
37
9258
9262
none
Distefano, G., Comotti, A., Bracco, S., Beretta, M., Sozzani, P. (2012). Porous Dipeptide Crystals as Polymerization Nanoreactors. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51(37), 9258-9262 [10.1002/anie.201204178].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/36497
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