Three alkanes and two ethers were oxidized with ozone in dichloromethane solution or in aqueous pH 3 suspension. Cyclodecane and cyclododecane were converted into the corresponding cycloalkanones. n-decane was converted into a mixture of isomeric n-decanones and carboxylic acids. An ester was,formed from the ethers. Hence, one of the methylene groups of these substrates is generally converted into a carbonyl group. Some of these reactions have preparative value.

Rindone, B., Saliu, F., & Bertoa, R. (2008). Functionalization of the unactivated carbon-hydrogen bond via ozonation. OZONE: SCIENCE & ENGINEERING, 30(2), 165-171 [10.1080/01919510701864221].

Functionalization of the unactivated carbon-hydrogen bond via ozonation

RINDONE, BRUNO;SALIU, FRANCESCO;
2008

Abstract

Three alkanes and two ethers were oxidized with ozone in dichloromethane solution or in aqueous pH 3 suspension. Cyclodecane and cyclododecane were converted into the corresponding cycloalkanones. n-decane was converted into a mixture of isomeric n-decanones and carboxylic acids. An ester was,formed from the ethers. Hence, one of the methylene groups of these substrates is generally converted into a carbonyl group. Some of these reactions have preparative value.
Articolo in rivista - Articolo scientifico
Ozone, Oxidation, Chemical Synthesis, Alkane Oxidation, Ether Oxidation, Reaction Mechanisms
English
165
171
7
Rindone, B., Saliu, F., & Bertoa, R. (2008). Functionalization of the unactivated carbon-hydrogen bond via ozonation. OZONE: SCIENCE & ENGINEERING, 30(2), 165-171 [10.1080/01919510701864221].
Rindone, B; Saliu, F; Bertoa, R
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/36134
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