The anion [HFe3Rh(CO)12]2− was obtained by reaction of [HFe(CO)4]− with Rh2(CO)4Cl2 in refluxing THF. Its solid state structure consists of a tetrahedron of metal atoms with three edge-bridging and nine terminal carbonyl groups. The hydridic ligand bridges a face containing the rhodium atom.

DELLA PERGOLA, R., Garlaschelli, L., Demartin, F., Manassero, M., Masciocchi, N., Longoni, G. (1988). Synthesis and Crystal-Structure of [NET4]2[HFE3RH(CO)12], the 1st Tetranuclear Fe-Rh Hydridocarbonyl Cluster. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 352(3), C59-C62 [10.1016/0022-328X(88)83134-6].

Synthesis and Crystal-Structure of [NET4]2[HFE3RH(CO)12], the 1st Tetranuclear Fe-Rh Hydridocarbonyl Cluster

DELLA PERGOLA, ROBERTO;
1988

Abstract

The anion [HFe3Rh(CO)12]2− was obtained by reaction of [HFe(CO)4]− with Rh2(CO)4Cl2 in refluxing THF. Its solid state structure consists of a tetrahedron of metal atoms with three edge-bridging and nine terminal carbonyl groups. The hydridic ligand bridges a face containing the rhodium atom.
Articolo in rivista - Articolo scientifico
hydride ligand; iron; rhodium; heterometallic cluster
English
1988
352
3
C59
C62
none
DELLA PERGOLA, R., Garlaschelli, L., Demartin, F., Manassero, M., Masciocchi, N., Longoni, G. (1988). Synthesis and Crystal-Structure of [NET4]2[HFE3RH(CO)12], the 1st Tetranuclear Fe-Rh Hydridocarbonyl Cluster. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 352(3), C59-C62 [10.1016/0022-328X(88)83134-6].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/35000
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