The anionic species [Ir12(m-CO)8(CO)18]2-, obtained by reaction of [Ir6(CO)15]2- with [Cu(CH3CN)4][BF4], contains a Ir12 metallic array formed by superimposition of three face-sharing octahedral units. The compound adopts a metal framework similar to that of [H2Rh12(C0)25] but possesses a different number of valence electrons.
DELLA PERGOLA, R., Demartin, F., Garlaschelli, L., Manassero, M., Martinengo, S., Sansoni, M. (1987). Chemistry of Iridium Carbonyl Cluster Complexes - Synthesis and X-Ray Crystal-Structure of [PPH4]2[IR12(MU-CO)8(CO)18], the 1st Example of a Medium-Size Iridium Carbonyl Cluster Complex. INORGANIC CHEMISTRY, 26(21), 3487-3491 [10.1021/ic00268a016].
Chemistry of Iridium Carbonyl Cluster Complexes - Synthesis and X-Ray Crystal-Structure of [PPH4]2[IR12(MU-CO)8(CO)18], the 1st Example of a Medium-Size Iridium Carbonyl Cluster Complex
DELLA PERGOLA, ROBERTO;
1987
Abstract
The anionic species [Ir12(m-CO)8(CO)18]2-, obtained by reaction of [Ir6(CO)15]2- with [Cu(CH3CN)4][BF4], contains a Ir12 metallic array formed by superimposition of three face-sharing octahedral units. The compound adopts a metal framework similar to that of [H2Rh12(C0)25] but possesses a different number of valence electrons.
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