Isomer shift (δ) and quadrupole splitting (Δ) parameters have been assigned to the iron sites in [FeRh5(CO)16]−, trans- and cis-[Fe2Rh4(CO)16]2−, [Fe3-Rh3(CO)17]3−, [FeRh4(CO)15]2−, [Fe3Pt3(CO)15]2− and [Fe4M(CO)16]2− (M = Pd or Pt) from 57Fe Mössbauer spectra recorded at 78 K. The data for the closo compounds [FeRh5(CO)16]− and [Fe2Rh4(CO)16]2− are compared with those for [Fe6(CO)16C]2−. In [Fe3Rh3(CO)17]3−, the three major Fe sites were identified. For both [Fe4M(CO)16]2− compounds two isomers were shown to be present in the solid state.

Brint, R., Collins, M., Spalding, T., Deeney, F., Longoni, G., & DELLA PERGOLA, R. (1987). MOSSBAUER STUDY OF SOME FE-CONTAINING M-6 AND M-5 CLUSTERS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 319(2), 219-228 [10.1016/0022-328X(87)83029-2].

MOSSBAUER STUDY OF SOME FE-CONTAINING M-6 AND M-5 CLUSTERS

DELLA PERGOLA, ROBERTO
1987

Abstract

Isomer shift (δ) and quadrupole splitting (Δ) parameters have been assigned to the iron sites in [FeRh5(CO)16]−, trans- and cis-[Fe2Rh4(CO)16]2−, [Fe3-Rh3(CO)17]3−, [FeRh4(CO)15]2−, [Fe3Pt3(CO)15]2− and [Fe4M(CO)16]2− (M = Pd or Pt) from 57Fe Mössbauer spectra recorded at 78 K. The data for the closo compounds [FeRh5(CO)16]− and [Fe2Rh4(CO)16]2− are compared with those for [Fe6(CO)16C]2−. In [Fe3Rh3(CO)17]3−, the three major Fe sites were identified. For both [Fe4M(CO)16]2− compounds two isomers were shown to be present in the solid state.
Articolo in rivista - Articolo scientifico
Mossbauer spectroscopy; heterometallic custers; iron; molecular geometry
English
Brint, R., Collins, M., Spalding, T., Deeney, F., Longoni, G., & DELLA PERGOLA, R. (1987). MOSSBAUER STUDY OF SOME FE-CONTAINING M-6 AND M-5 CLUSTERS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 319(2), 219-228 [10.1016/0022-328X(87)83029-2].
Brint, R; Collins, M; Spalding, T; Deeney, F; Longoni, G; DELLA PERGOLA, R
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/34918
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