In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany

Arrigoni, A., Ceriotti, A., DELLA PERGOLA, R., Longoni, G., Manassero, M., Masciocchi, N., et al. (1984). Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH, 23(4), 322-323 [10.1002/anie.198403221].

Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−

DELLA PERGOLA, ROBERTO;
1984

Abstract

In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
Articolo in rivista - Articolo scientifico
cobalt; nickel; interstitial carbide; C-C bond heterometallic cluster
English
322
323
2
Arrigoni, A., Ceriotti, A., DELLA PERGOLA, R., Longoni, G., Manassero, M., Masciocchi, N., et al. (1984). Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH, 23(4), 322-323 [10.1002/anie.198403221].
File in questo prodotto:
File Dimensione Formato  
11_co6ni2.pdf

accesso aperto

Dimensione 1.09 MB
Formato Adobe PDF
1.09 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/34297
Citazioni
  • Scopus 36
  • ???jsp.display-item.citation.isi??? 38
Social impact