In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany

Arrigoni, A., Ceriotti, A., DELLA PERGOLA, R., Longoni, G., Manassero, M., Masciocchi, N., et al. (1984). SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DICARBIDO BIMETALLIC CLUSTER [CO6NI2C2(CO)16]2-. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH, 23(4), 322-323 [10.1002/anie.198403221].

SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DICARBIDO BIMETALLIC CLUSTER [CO6NI2C2(CO)16]2-

DELLA PERGOLA, ROBERTO;
1984

Abstract

In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
Articolo in rivista - Articolo scientifico
cobalt; nickel; interstitial carbide; C-C bond heterometallic cluster
English
Arrigoni, A., Ceriotti, A., DELLA PERGOLA, R., Longoni, G., Manassero, M., Masciocchi, N., et al. (1984). SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DICARBIDO BIMETALLIC CLUSTER [CO6NI2C2(CO)16]2-. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH, 23(4), 322-323 [10.1002/anie.198403221].
Arrigoni, A; Ceriotti, A; DELLA PERGOLA, R; Longoni, G; Manassero, M; Masciocchi, N; Sansoni, M
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/34297
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