Subtilisin-catalyzed esterification of several enatiomeric benzyl and naphthyl glycopyranosides has been investigated. The D-sugar derivatives were all good substrates and subtilisin regioselectivity was similar with all the compounds tested, the 3-OH being acylated predominantly. On the other hand, most of the L-glycopyranosides were transformed during longer reaction times with a lower regioselectivity, the 2-OH being preferentially but not exclusively acylated
Danieli, B., Peri, F., Roda, G., Carrea, G., & Riva, S. (1999). On the regioselectivity of the protease Subtilisin towards the acylation of enantiomeric pairs of benzyl and naphtyl glycopyranosides. Part 2. TETRAHEDRON, 55(7), 2045-2060.
Citazione: | Danieli, B., Peri, F., Roda, G., Carrea, G., & Riva, S. (1999). On the regioselectivity of the protease Subtilisin towards the acylation of enantiomeric pairs of benzyl and naphtyl glycopyranosides. Part 2. TETRAHEDRON, 55(7), 2045-2060. |
Tipo: | Articolo in rivista - Articolo scientifico |
Carattere della pubblicazione: | Scientifica |
Presenza di un coautore afferente ad Istituzioni straniere: | No |
Titolo: | On the regioselectivity of the protease Subtilisin towards the acylation of enantiomeric pairs of benzyl and naphtyl glycopyranosides. Part 2 |
Autori: | Danieli, B; Peri, F; Roda, G; Carrea, G; Riva, S |
Autori: | |
Data di pubblicazione: | 1999 |
Lingua: | English |
Rivista: | TETRAHEDRON |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/S0040-4020(98)01217-4 |
Appare nelle tipologie: | 01 - Articolo su rivista |