The syntheses and interconversions of mixed iron-rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh4(CO)15]2-, [FeRh5(CO)16]-, and [Fe2Rh4(C0)16]2- which can all be obtained from the unstable cluster, [Fe2Rh(CO)x]-

Ceriotti, A., Longoni, G., Manassero, M., Sansoni, M., DELLA PERGOLA, R., Heaton, B., et al. (1982). BIMETALLIC IRON-RHODIUM ANIONIC CARBONYL CLUSTERS [FE2RH(CO)X]- (X = 10 OR 11), [FERH4(CO)15]2-, [FE2RH4(CO)16]2-, AND [FERH5(CO)16]-. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS(15), 886-887 [10.1039/c39820000886].

BIMETALLIC IRON-RHODIUM ANIONIC CARBONYL CLUSTERS [FE2RH(CO)X]- (X = 10 OR 11), [FERH4(CO)15]2-, [FE2RH4(CO)16]2-, AND [FERH5(CO)16]-

DELLA PERGOLA, ROBERTO;
1982

Abstract

The syntheses and interconversions of mixed iron-rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh4(CO)15]2-, [FeRh5(CO)16]-, and [Fe2Rh4(C0)16]2- which can all be obtained from the unstable cluster, [Fe2Rh(CO)x]-
Articolo in rivista - Articolo scientifico
iron; rhodium; heterometallic clusters; Multinuclear NMR
English
Ceriotti, A., Longoni, G., Manassero, M., Sansoni, M., DELLA PERGOLA, R., Heaton, B., et al. (1982). BIMETALLIC IRON-RHODIUM ANIONIC CARBONYL CLUSTERS [FE2RH(CO)X]- (X = 10 OR 11), [FERH4(CO)15]2-, [FE2RH4(CO)16]2-, AND [FERH5(CO)16]-. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS(15), 886-887 [10.1039/c39820000886].
Ceriotti, A; Longoni, G; Manassero, M; Sansoni, M; DELLA PERGOLA, R; Heaton, B; Smith, D
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/32988
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