The syntheses and interconversions of mixed iron-rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh4(CO)15]2-, [FeRh5(CO)16]-, and [Fe2Rh4(C0)16]2- which can all be obtained from the unstable cluster, [Fe2Rh(CO)x]-
Ceriotti, A., Longoni, G., Manassero, M., Sansoni, M., DELLA PERGOLA, R., Heaton, B., et al. (1982). BIMETALLIC IRON-RHODIUM ANIONIC CARBONYL CLUSTERS [FE2RH(CO)X]- (X = 10 OR 11), [FERH4(CO)15]2-, [FE2RH4(CO)16]2-, AND [FERH5(CO)16]-. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS(15), 886-887 [10.1039/c39820000886].
BIMETALLIC IRON-RHODIUM ANIONIC CARBONYL CLUSTERS [FE2RH(CO)X]- (X = 10 OR 11), [FERH4(CO)15]2-, [FE2RH4(CO)16]2-, AND [FERH5(CO)16]-
DELLA PERGOLA, ROBERTO;
1982
Abstract
The syntheses and interconversions of mixed iron-rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh4(CO)15]2-, [FeRh5(CO)16]-, and [Fe2Rh4(C0)16]2- which can all be obtained from the unstable cluster, [Fe2Rh(CO)x]-
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