Reaction of K[(eta-3-C7H7)Fe(CO)3] with [(1,5-eta-4-C8H12)Pd(eta-5-C5H5)]BF4 gives the title compound which is the first case of a bridging cycloheptatrienyl metal-metal bonded complex having an uncoordinated double bond in the ring and detectable low-temperature limiting H-1 and C-13 NMR spectra.

Airoldi, M., Deganello, G., Gennaro, G., Moret, M., Sironi, A. (1992). SYNTHESIS, FLUXIONAL BEHAVIOR AND X-RAY CRYSTAL-STRUCTURE OF [FE(CO)3(MU-ETA-3-ETA-2-C7H7)PD(ETA-5-C5H5)]. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS(11), 850-851 [10.1039/c39920000850].

SYNTHESIS, FLUXIONAL BEHAVIOR AND X-RAY CRYSTAL-STRUCTURE OF [FE(CO)3(MU-ETA-3-ETA-2-C7H7)PD(ETA-5-C5H5)]

MORET, MASSIMO;
1992

Abstract

Reaction of K[(eta-3-C7H7)Fe(CO)3] with [(1,5-eta-4-C8H12)Pd(eta-5-C5H5)]BF4 gives the title compound which is the first case of a bridging cycloheptatrienyl metal-metal bonded complex having an uncoordinated double bond in the ring and detectable low-temperature limiting H-1 and C-13 NMR spectra.
Articolo in rivista - Articolo scientifico
PALLADIUM COMPLEXES
English
1992
11
850
851
none
Airoldi, M., Deganello, G., Gennaro, G., Moret, M., Sironi, A. (1992). SYNTHESIS, FLUXIONAL BEHAVIOR AND X-RAY CRYSTAL-STRUCTURE OF [FE(CO)3(MU-ETA-3-ETA-2-C7H7)PD(ETA-5-C5H5)]. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS(11), 850-851 [10.1039/c39920000850].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/32924
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