Trichlorobis(cyclohexyl isocyanide)bis(dimethyl-phenylphosphine)rhenium(III) has been synthesized from [ReOCl3(CNCy)2] (Cy = cyclohexyl) by the removal of oxygen with excess dimethylphenylphosphine. The structure of its 1,2-dichlorobenzene adduct, determined by single-crystal X-ray methods, has a monocapped octahedral arrangement (idealized C(s) symmetry) of the seven ligands about the Re atom; the three Cl atoms adopt a fac geometry, opposite the face capped by one isocyanide ligand.

Masciocchi, N., Moret, M., Ardizzoia, G., Lamonica, G. (1995). [RECL3(C8H11P)2(C7H11N)2]CENTER-DOT-C6H4CL2. ACTA CRYSTALLOGRAPHICA. SECTION C, CRYSTAL STRUCTURE COMMUNICATIONS, 51, 201-203 [10.1107/S0108270194007420].

[RECL3(C8H11P)2(C7H11N)2]CENTER-DOT-C6H4CL2

MORET, MASSIMO;
1995

Abstract

Trichlorobis(cyclohexyl isocyanide)bis(dimethyl-phenylphosphine)rhenium(III) has been synthesized from [ReOCl3(CNCy)2] (Cy = cyclohexyl) by the removal of oxygen with excess dimethylphenylphosphine. The structure of its 1,2-dichlorobenzene adduct, determined by single-crystal X-ray methods, has a monocapped octahedral arrangement (idealized C(s) symmetry) of the seven ligands about the Re atom; the three Cl atoms adopt a fac geometry, opposite the face capped by one isocyanide ligand.
Articolo in rivista - Articolo scientifico
COMPLEX; RHENIUM; REACTIVITY
English
1995
51
201
203
none
Masciocchi, N., Moret, M., Ardizzoia, G., Lamonica, G. (1995). [RECL3(C8H11P)2(C7H11N)2]CENTER-DOT-C6H4CL2. ACTA CRYSTALLOGRAPHICA. SECTION C, CRYSTAL STRUCTURE COMMUNICATIONS, 51, 201-203 [10.1107/S0108270194007420].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/32878
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