Phthalimidomethyl and phenoxymethyl as well as corresponding acetyl cobalt tetracarbonyls (1-4) were prepared and characterized. The single-crystal X-ray diffraction molecular structure of 1 (the first X-ray structure of an alkylcobalt tetracarbonyl with a pure organic alkyl group) was determined. The equilibrium constants of the equilibria 1 half arrow pointing right over half arrow pointing left 2 and 3 half arrow pointing right over half arrow pointing left 4 were determined at 20-60 and 20-40 degrees C, respectively

Nagygergely, I., Szalontai, G., Ungvary, F., Marko, L., Moret, M., Sironi, A., et al. (1997). (Phthalimidomethyl)- and (phenoxymethyl)cobalt carbonyls. Equilibria of CO insertion. ORGANOMETALLICS, 16(12), 2740-2742 [10.1021/om9700066].

(Phthalimidomethyl)- and (phenoxymethyl)cobalt carbonyls. Equilibria of CO insertion

Moret, M;
1997

Abstract

Phthalimidomethyl and phenoxymethyl as well as corresponding acetyl cobalt tetracarbonyls (1-4) were prepared and characterized. The single-crystal X-ray diffraction molecular structure of 1 (the first X-ray structure of an alkylcobalt tetracarbonyl with a pure organic alkyl group) was determined. The equilibrium constants of the equilibria 1 half arrow pointing right over half arrow pointing left 2 and 3 half arrow pointing right over half arrow pointing left 4 were determined at 20-60 and 20-40 degrees C, respectively
Articolo in rivista - Articolo scientifico
alkylcobalt carbonyls; metal-complexes; tetracarbonyl; cobalt; methylcobalt; acetylcobalt; monoxide
English
1997
16
12
2740
2742
none
Nagygergely, I., Szalontai, G., Ungvary, F., Marko, L., Moret, M., Sironi, A., et al. (1997). (Phthalimidomethyl)- and (phenoxymethyl)cobalt carbonyls. Equilibria of CO insertion. ORGANOMETALLICS, 16(12), 2740-2742 [10.1021/om9700066].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/32848
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