The reaction of [IrH3(AsPh3)2(CNC6H 4Me-p)] with carboxylic acids yields the new paramagnetic iridium(II) complexes [Ir(AsPh3)(CNC6H4Me-p)(O2CR) 2] [R = Me, p-ClC6H4, p-MeOC6H4, 2,4,6-Me3C6H2; RCO2 = pentane-2,4-dionate (pd)]. Their characterisation has been carried out by spectroscopic and magnetic measurements. The structure of the complexes and the ground-state electronic configuration of IrII therein is discussed.

Araneo, A., Morazzoni, F., Napoletano, T. (1975). PARAMAGNETIC BIS(CARBOXYLATO) (PARA-TOLYL ISOCYANIDE)TRIPHENYLARSINEIRIDIUM(II) COMPLEXES - PREPARATION AND CHARACTERIZATION BY SPECTROSCOPIC AND MAGNETIC MEASUREMENTS. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS(20), 2039-2041 [10.1039/dt9750002039].

PARAMAGNETIC BIS(CARBOXYLATO) (PARA-TOLYL ISOCYANIDE)TRIPHENYLARSINEIRIDIUM(II) COMPLEXES - PREPARATION AND CHARACTERIZATION BY SPECTROSCOPIC AND MAGNETIC MEASUREMENTS

MORAZZONI, FRANCA;
1975

Abstract

The reaction of [IrH3(AsPh3)2(CNC6H 4Me-p)] with carboxylic acids yields the new paramagnetic iridium(II) complexes [Ir(AsPh3)(CNC6H4Me-p)(O2CR) 2] [R = Me, p-ClC6H4, p-MeOC6H4, 2,4,6-Me3C6H2; RCO2 = pentane-2,4-dionate (pd)]. Their characterisation has been carried out by spectroscopic and magnetic measurements. The structure of the complexes and the ground-state electronic configuration of IrII therein is discussed.
Articolo in rivista - Articolo scientifico
BIS(CARBOXYLATO) (PARA-TOLYL ISOCYANIDE)TRIPHENYLARSINEIRIDIUM(II), EPR,
English
1975
20
2039
2041
none
Araneo, A., Morazzoni, F., Napoletano, T. (1975). PARAMAGNETIC BIS(CARBOXYLATO) (PARA-TOLYL ISOCYANIDE)TRIPHENYLARSINEIRIDIUM(II) COMPLEXES - PREPARATION AND CHARACTERIZATION BY SPECTROSCOPIC AND MAGNETIC MEASUREMENTS. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS(20), 2039-2041 [10.1039/dt9750002039].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/32753
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