Different reaction temperatures have allowed the isolation of 1:1 and 1:2 adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine. Thermal, vibrational, and magnetic-susceptibility analyses have provided useful information about the structural properties of these complexes; e.s.r. and electronic spectra have permitted a detailed investigation of the ligand-field levels of the cobalt atom. All the adducts react with oxygen and form, at low temperatures, well characterized Co:O<inf>2</inf> 1:1 adducts.
Cariati, F., Galizzioli, D., Morazzoni, F., Busetto, C. (1975). NEW ADDUCTS OF PHTHALOCYANINATOCOBALT(II) WITH PYRIDINE AND 4-METHYL-PYRIDINE AND THEIR VIBRATIONAL, MAGNETIC, AND ELECTRONIC PROPERTIES .1. REACTIVITY TOWARDS OXYGEN. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS(7), 556-561 [10.1039/dt9750000556].
NEW ADDUCTS OF PHTHALOCYANINATOCOBALT(II) WITH PYRIDINE AND 4-METHYL-PYRIDINE AND THEIR VIBRATIONAL, MAGNETIC, AND ELECTRONIC PROPERTIES .1. REACTIVITY TOWARDS OXYGEN
MORAZZONI, FRANCA;
1975
Abstract
Different reaction temperatures have allowed the isolation of 1:1 and 1:2 adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine. Thermal, vibrational, and magnetic-susceptibility analyses have provided useful information about the structural properties of these complexes; e.s.r. and electronic spectra have permitted a detailed investigation of the ligand-field levels of the cobalt atom. All the adducts react with oxygen and form, at low temperatures, well characterized Co:O
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