Rhodium-103 decoupled 13C n.m.r. measurements have been used to assign the l3C n.m.r of [NiRh6(CO)16]2- and variable-temperature measurements establish a completely different fluxional behaviour to that found for the isostructural cluster, [Rh7(Co)16]3-.
Heaton, B., DELLA PERGOLA, R., Strona, L., Smith, D., Fumagalli, A. (1982). C-13-LABELED [RH-103] NUCLEAR MAGNETIC-RESONANCE STUDIES AND FLUXIONAL BEHAVIOR OF THE NICKEL CAPPED RHODIUM CLUSTER [NIRH6(CO)16]2-. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS(12), 2553-2555 [10.1039/DT9820002553].
C-13-LABELED [RH-103] NUCLEAR MAGNETIC-RESONANCE STUDIES AND FLUXIONAL BEHAVIOR OF THE NICKEL CAPPED RHODIUM CLUSTER [NIRH6(CO)16]2-
DELLA PERGOLA, ROBERTO;
1982
Abstract
Rhodium-103 decoupled 13C n.m.r. measurements have been used to assign the l3C n.m.r of [NiRh6(CO)16]2- and variable-temperature measurements establish a completely different fluxional behaviour to that found for the isostructural cluster, [Rh7(Co)16]3-.
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