The three isomeric forms of the compound [OsCl3(AsPh3)(p-CH3C6H4NC)2] have been isolated and their probable structures deduced by comparative use of vibrational, electronic, and magnetic measurements. The ground-state configuration of osmium(III) ion in a low-symmetry field is proposed and the perturbing influence of the isocyanide ligand on the metal center is discussed. The differences in the electronic distribution of the isomeric species are also considered. © 1977, American Chemical Society. All rights reserved.
Araneo, A., Mercati, G., Morazzoni, F., Napoletano, T. (1977). SPECTROSCOPIC AND SPECTROMAGNETIC STUDY OF TRICHLORO(TRIPHENYLARSINE)BIS(PARA-TOLYL ISOCYANIDE)OSMIUM(III) - CHARACTERIZATION OF 3 ISOMERIC FORMS. INORGANIC CHEMISTRY, 16(5), 1196-1201 [10.1021/ic50171a044].
SPECTROSCOPIC AND SPECTROMAGNETIC STUDY OF TRICHLORO(TRIPHENYLARSINE)BIS(PARA-TOLYL ISOCYANIDE)OSMIUM(III) - CHARACTERIZATION OF 3 ISOMERIC FORMS
MORAZZONI, FRANCA;
1977
Abstract
The three isomeric forms of the compound [OsCl3(AsPh3)(p-CH3C6H4NC)2] have been isolated and their probable structures deduced by comparative use of vibrational, electronic, and magnetic measurements. The ground-state configuration of osmium(III) ion in a low-symmetry field is proposed and the perturbing influence of the isocyanide ligand on the metal center is discussed. The differences in the electronic distribution of the isomeric species are also considered. © 1977, American Chemical Society. All rights reserved.
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