The reaction of Fe2S2(CO)6 and PPh3 affords Fe2S2(CO)4(PPh3)2 by an unprecedented mechanism involving the intermediacy of SPPh3 and Fe2S(CO)6(PPh3)2.
Zhang, F., Woods, T., Rauchfuss, T., Arrigoni, F., Zampella, G. (2021). CO substitution by PPh3in Fe2S2(CO)6proceeds via a novel Fe2S intermediate. CHEMICAL COMMUNICATIONS, 57(41), 5079-5081 [10.1039/d1cc00956g].
CO substitution by PPh3in Fe2S2(CO)6proceeds via a novel Fe2S intermediate
Arrigoni F.;Zampella G.
2021
Abstract
The reaction of Fe2S2(CO)6 and PPh3 affords Fe2S2(CO)4(PPh3)2 by an unprecedented mechanism involving the intermediacy of SPPh3 and Fe2S(CO)6(PPh3)2.
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